You are confusing expense-reimbursement policies with tax issues. If your employees are required to account to you for their business expenses, then they do not report the amounts you pay them as reimbursement as taxable income; you tax the deduction for these payments not as wages but as travel expenses. You can pay them whatever you choose to pay and they will accept. If you pay more than the IRS rate, to which you refer, the excess will be taxable to them.
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