If I dont give my employer permission to take my photograph and put it on his website and he fires me is that Legal? Can I colect unemployment?

As a general matter, an employee is employed on an "at will" basis, which means that the employer may fire him at any time for any reason or no reason at all. I provided this answer to you in your previous inquiry about the same subject. If you are fired and make an application for unemployment compensation, your employer will likely contest the claim on the ground that you were insubordinate by withholding your consent.