Can I file for Green Card, being considered as US Resident Alien as per IRS?

Being a permanent resident for purposes of U. S. taxes is not the same as being a permanent resident in the eyes of the Department of Homeland Security. You would have to qualify under a recognized basis such as family relationship, employment-based immigration, asylum, investment, etc. Due to the limitations of the Lawyers.com Forums, Alan Lee, Esq.'s (the "Firm") participation in responding to questions posted herein does not constitute legal advice, nor legal representation of the person or entity posting a question. No Attorney/Client relationship is or shall be construed to be created hereby. The information provided herein by the Firm is general, and requires that the poster obtain specific legal advice from an attorney. The poster shall not rely upon the information provided herein as legal advice nor as the basis for making any decisions of legal consequence.