Hello.
I am sorry to hear about your circumstance however all visa waiver entrants are subject to removal without the opportunity to go before an immigration judge if they violate their status, including overstaying.
Assuming you are a United States citizen, had you still been legally married you could have prevented his removal by applying for adjustment of status.
Contact the ICE officials where he is being detained to see if they will allow time for you to remarry him and file for adjustment. It will be difficult but it is worth the chance.
If you need assistance please contact my office for a free consultation.
Answered on Feb 10th, 2016 at 12:56 PM