For an illegal alien crossing theborder for the first time , who is now married to a united states citizen , is there anyway to do paper work for gree

Most likely not. In order to adjust status to lawful permanent resident, an alien must either be inspected and admitted or paroled into the U.S. Being married to a U.S. citizen does not excuse you from this requirement. The provisional waiver may be a viable option for you. You can read more about family immigration at http://myattorneyusa.com/family-immigration.