If she is a US citizen and you are legally married under the laws of the state where you got married, then she can petition for you and you will be immediately eligible for green card processing. however, if she is only a permanent resident, she can petition for you but you will have to wait until the priority date is current to apply for the green card. Furthermore, you would have to be in the US in valid status and not an overstay in order to apply for adjustment of status once the priority date becomes current.
Answered on Jul 16th, 2014 at 8:33 AM